FREE BOOKS

Author's List




PREV.   NEXT  
|<   59   60   61   62   63   64   65   66   67   68   69   70   71   72   73   74   75   76   77   78   79   80   81   82   83  
84   85   86   87   88   89   90   91   92   93   94   95   96   97   98   99   100   101   102   103   104   105   106   107   108   >>   >|  
roperties to isomaltose. =Cellobiose= is a disaccharide which results from the hydrolysis of cellulose. It is a reducing sugar, forms an osazone, and resembles maltose. Maltose, isomaltose, gentiobiose, and cellobiose, are all glucose-glucosides, the difference between them being undoubtedly due to linkage being between different alcoholic groups in the glucose molecules. The disaccharide =lactose= is a glucose-galactoside. It is the sugar which is present in the milk of all mammals. It has never been found in plants. =Melibiose=, which is the corresponding vegetable glucose-galactoside, may be obtained by the partial hydrolysis of the trisaccharide _raffinose_ (see below). It is a reducing sugar; forms a characteristic osazone; and exhibits mutarotation. It is not fermented by ordinary top-yeasts, but is first hydrolyzed and then fermented by the enzymes present in bottom-yeasts. TRISACCHARIDES Trisaccharides, as the name indicates, consist of three hexoses (or monosaccharides) linked together by the dropping out of two molecules of water. Their formula is C_{18}H_{32}O_{16}. When completely hydrolyzed, they yield three molecules of monosaccharides; when partially hydrolyzed, one each of a disaccharide and a monosaccharide. One trisaccharide of the reducing sugar type, namely _rhamnose_, exists in plants as a constituent of the glucoside xanthorhamnin. It is composed of one molecule of glucose united to two molecules of rhamnose (methyl pentose, C_{6}H_{12}O_{5}). It is of interest only in connection with the properties of the glucoside in which it is present (see page 84). Three trisaccharides which are non-reducing sugars are found in plants; namely, raffinose, gentianose, and melizitose. =Raffinose= occurs normally in cotton seeds, in barley grains, and in manna; also, in small quantities in the beet root, associated with sucrose. It is more soluble in water than is sucrose and hence remains in solution in the molasses from beet-sugar manufacture, which constitutes the commercial source for this sugar. Raffinose crystallizes out of concentrated solutions, with five molecules of water of crystallization, in clusters of glistening prisms. It is strongly dextrorotatory, the anhydrous sugar having a specific rotatory power of +185 deg., and the crystalline form, C_{18}H_{32}O_{16}, showing a specific rotation of +104.5 deg. It does not reduce Fehling's solution, nor form an o
PREV.   NEXT  
|<   59   60   61   62   63   64   65   66   67   68   69   70   71   72   73   74   75   76   77   78   79   80   81   82   83  
84   85   86   87   88   89   90   91   92   93   94   95   96   97   98   99   100   101   102   103   104   105   106   107   108   >>   >|  



Top keywords:

glucose

 

molecules

 

reducing

 
plants
 
hydrolyzed
 

present

 

disaccharide

 

monosaccharides

 

yeasts

 

trisaccharide


raffinose

 

fermented

 

sucrose

 
solution
 
specific
 

Raffinose

 
rhamnose
 

glucoside

 

isomaltose

 
hydrolysis

galactoside

 

osazone

 

remains

 

grains

 

barley

 

quantities

 
soluble
 

cotton

 

properties

 
roperties

connection

 

trisaccharides

 
occurs
 

cellobiose

 
melizitose
 

gentianose

 

sugars

 

manufacture

 

Maltose

 

crystalline


maltose

 

gentiobiose

 

rotatory

 

showing

 

rotation

 
Fehling
 
reduce
 

anhydrous

 

crystallizes

 
source