FREE BOOKS

Author's List




PREV.   NEXT  
|<   55   56   57   58   59   60   61   62   63   64   65   66   67   68   69   70   71   72   73   74   75   76   77   78   79  
80   81   82   83   84   85   86   87   88   89   90   91   92   93   94   95   96   97   98   99   100   101   102   103   104   >>   >|  
eta], C_{24}H_{42}O_{21} (previously named by Prior, achroodextrin III.). They also separated a substance, C_{12}H_{22}O_{11}, isomeric with maltose, which had, however, the characteristics of a dextrin. This is probably identical with the so-called dextrinose isolated by V. Syniewski in 1902, which yields a phenylosazone melting at 82-83 deg. C. It has been proved by H. Ost that the so-called isomaltose of Lintner is a mixture of maltose and another substance, maltodextrin, isomeric with Ling and Baker's maltodextrin-[beta]. The theory of Brown and Morris of the degradation of starch, although based on experimental evidence of some weight, is by no means universally accepted. Nevertheless it is of considerable interest, as it offers a rational and consistent explanation of the phenomena known to accompany the transformation of starch by diastase, and even if not strictly correct it has, at any rate, proved itself to be a practical working hypothesis, by which the mashing and fermenting operations may be regulated and controlled. According to Brown and Morris, the starch molecule consists of five amylin groups, each of which corresponds to the molecular formula (C_{12}H_{20}O_{10})_{20}. Four of these amylin radicles are grouped centrally round the fifth, thus:-- (C_{12}H_{20}O_{10})_{20} (C_{12}H_{20}O_{10})_{20} \ / (C_{12}H_{20}O_{10})_{20} / \ (C_{12}H_{20}O_{10})_{20} (C_{12}H_{20}O_{10})_{20} By the action of diastase, this complex molecule is split up, undergoing hydrolysis into four groups of amyloins, the fifth or central group remaining unchanged (and under brewing conditions unchangeable), forming the substance known as stable dextrin. When diastase acts on starch-paste, hydrolysis proceeds as far as the reaction represented by the following equation:-- 5(C_{12}H_{20}O_{10})_{20} + 80 H_2O starch. water. = 80 C_{12}H_{22}O_{11} + (C_{12}H_{20}O_{10})_{20} maltose. stable dextrin. The amyloins are substances containing varying numbers of amylin (original starch or dextrin) groups in conjunction with a proportional number of maltose groups. They are not separable into maltose and dextrin by any of the ordinary means, but exhibit the properties of mixtures of these subs
PREV.   NEXT  
|<   55   56   57   58   59   60   61   62   63   64   65   66   67   68   69   70   71   72   73   74   75   76   77   78   79  
80   81   82   83   84   85   86   87   88   89   90   91   92   93   94   95   96   97   98   99   100   101   102   103   104   >>   >|  



Top keywords:

starch

 

dextrin

 

maltose

 

groups

 

amylin

 

diastase

 

substance

 

amyloins

 

hydrolysis

 

Morris


maltodextrin
 

proved

 

stable

 
isomeric
 

molecule

 

called

 

regulated

 

complex

 
controlled
 

According


consists

 

formula

 
grouped
 

radicles

 

centrally

 
molecular
 

corresponds

 

action

 

conditions

 

varying


numbers
 

original

 
substances
 
conjunction
 

proportional

 

properties

 

mixtures

 

exhibit

 

number

 

separable


ordinary
 

equation

 

brewing

 

unchanged

 
remaining
 

central

 

unchangeable

 

forming

 

reaction

 
represented