FREE BOOKS

Author's List




PREV.   NEXT  
|<   330   331   332   333   334   335   336   337   338   339   340   341   342   343   344   345   346   347   348   349   350   351   352   353   354  
355   356   357   358   359   360   361   362   363   364   365   366   367   368   369   370   371   372   373   374   375   376   377   378   379   >>   >|  
ld be applied almost always as a top-dressing. _Loss of Nitric Acid._ The risks of the loss of nitrogen in the form of nitric acid, although not so great as they are in the case of ammonia, are still considerable. As nitric acid is not a base but an acid, what is to be avoided in mixing nitrates is bringing them in contact with any other manure which contains another free and stronger acid--as, for example, superphosphate. The free acid present in superphosphate has the tendency to drive out the nitric acid from the nitrate and usurp its place. The risk of loss of expulsion in the above cases is always augmented by the rise of temperature which invariably accompanies chemical action of any kind; and although the loss of nitrogen, in the form of nitric acid, caused by mixing superphosphate and nitrate of soda, might, under ordinary circumstances, amount to very little, yet, if the mixture were to be allowed to stand any time, and the temperature of the mass to be heightened, the loss which would undoubtedly then ensue would be considerable. The nitrogen salt which it is safe to mix with superphosphate is sulphate of ammonia. _Reversion of Phosphates._ But, as has already been mentioned, there is another loss which may result from the mixing of manures. This is the deterioration of the value of an ingredient by reason of change of chemical condition. This is a source of loss that was little suspected a number of years ago, but it is now well known that superphosphate of lime, under certain conditions, is changed from its soluble to an insoluble form. We have already referred to the reversion of phosphate in the chapter on the Manufacture of Superphosphates.[247] It was there pointed out that reversion is often caused by the presence of iron and alumina or undissolved phosphate, and that the risk of reversion is therefore very much less in a well-made article, made from pure raw material, than in one made from a raw phosphate containing much iron and alumina. Superphosphates containing a large percentage of insoluble phosphates ought not to be kept too long before being used as a manure, otherwise much of the labour and expense involved in their manufacture will be lost by the reversion of their soluble phosphate. Further, it is highly inadvisable to mix superphosphates with basic slag, which contains a large percentage of both iron and free lime. Lastly, if it is desired to mix superphosphate with insolubl
PREV.   NEXT  
|<   330   331   332   333   334   335   336   337   338   339   340   341   342   343   344   345   346   347   348   349   350   351   352   353   354  
355   356   357   358   359   360   361   362   363   364   365   366   367   368   369   370   371   372   373   374   375   376   377   378   379   >>   >|  



Top keywords:

superphosphate

 

reversion

 
nitric
 

phosphate

 

nitrogen

 

mixing

 
temperature
 
nitrate
 

Superphosphates

 

soluble


insoluble
 
alumina
 
caused
 

percentage

 

chemical

 

considerable

 
manure
 

ammonia

 

chapter

 

inadvisable


highly

 

Further

 

superphosphates

 

referred

 

Lastly

 

number

 

suspected

 

insolubl

 

desired

 

conditions


changed

 

manufacture

 

article

 

material

 

source

 
pointed
 
phosphates
 

presence

 

involved

 

labour


undissolved
 
expense
 

Manufacture

 

stronger

 

contact

 

nitrates

 
bringing
 

present

 
tendency
 

augmented