FREE BOOKS

Author's List




PREV.   NEXT  
|<   246   247   248   249   250   251   252   253   254   255   256   257   258   259   260   261   262   263   264   265   266   267   268   269   270  
271   272   273   274   275   276   277   278   279   280   281   282   283   284   285   286   287   288   289   290   291   292   293   294   295   >>   >|  
ty and color, the most abundant being hematite, which ranges in color from red to nearly black. When prepared by chemical processes it forms a red powder which is used as a paint pigment (Venetian red) and as a polishing powder (rouge). Magnetite has the formula Fe_{3}O_{4} and is a combination of FeO and Fe_{2}O_{3}. It is a very valuable ore, but is less abundant than hematite. It is sometimes called magnetic oxide of iron, or lodestone, since it is a natural magnet. ~Ferrous salts.~ These salts are obtained by dissolving iron in the appropriate acid, or, when insoluble, by precipitation. They are usually light green in color and crystallize well. In chemical reactions they are quite similar to the salts of magnesium and zinc, but differ from them in one important respect, namely, that they are easily changed into compounds in which the metal is trivalent. Thus ferrous chloride treated with chlorine or aqua regia is changed into ferric chloride: FeCl_{2} + Cl = FeCl_{3}. Ferrous hydroxide exposed to moist air is rapidly changed into ferric hydroxide: 2Fe(OH)_{2} + H_{2}O + O = 2Fe(OH)_{3}. ~Ferrous sulphate~ _(copperas, green vitriol)_ (FeSO_{4}.7H_{2}O). Ferrous sulphate is the most familiar ferrous compound. It is prepared commercially as a by-product in the steel-plate mills. Steel plates are cleaned by the action of dilute sulphuric acid upon them, and in the process some of the iron dissolves. The liquors are concentrated and the green vitriol separates from them. ~Ferrous sulphide~ (FeS). Ferrous sulphide is sometimes found in nature as a golden-yellow crystalline mineral. It is formed as a black precipitate when a soluble sulphide and an iron salt are brought together in solution: FeSO_{4} + Na_{2}S = FeS + Na_{2}SO_{4}. It can also be made as a heavy dark-brown solid by fusing together the requisite quantities of sulphur and iron. It is obtained as a by-product in the metallurgy of lead: PbS + Fe = FeS + Pb. It is used in the laboratory in the preparation of hydrosulphuric acid: FeS + 2HCl = FeCl_{2} + H_{2}S. ~Iron disulphide~ _(pyrites)_ (FeS_{2}). This substance bears the same relation to ferrous sulphide that hydrogen dioxide does to water. It occurs abundantly in nature in the form of brass-yellow cubical crystals and in compact masses. Sometimes the name "fool's gold" is applied to it from its superficial resemblance to the precious metal. It is used in v
PREV.   NEXT  
|<   246   247   248   249   250   251   252   253   254   255   256   257   258   259   260   261   262   263   264   265   266   267   268   269   270  
271   272   273   274   275   276   277   278   279   280   281   282   283   284   285   286   287   288   289   290   291   292   293   294   295   >>   >|  



Top keywords:
Ferrous
 

sulphide

 

changed

 

ferrous

 

yellow

 

vitriol

 

nature

 

sulphate

 
product
 

ferric


hydroxide

 

chloride

 

obtained

 

powder

 
hematite
 

chemical

 

prepared

 

abundant

 

Sometimes

 

soluble


applied

 

compact

 
precipitate
 

masses

 

formed

 
brought
 

solution

 

liquors

 

concentrated

 
separates

dissolves

 
process
 
crystalline
 

superficial

 
resemblance
 

precious

 

golden

 
mineral
 

cubical

 

hydrosulphuric


preparation

 
laboratory
 

hydrogen

 

relation

 

substance

 

disulphide

 
dioxide
 
pyrites
 
occurs
 

quantities