FREE BOOKS

Author's List




PREV.   NEXT  
|<   269   270   271   272   273   274   275   276   277   278   279   280   281   282   283   284   285   286   287   288   289   290   291   292   293  
294   295   296   297   298   299   300   301   302   303   304   305   306   307   308   309   310   311   312   313   314   >>  
omium hydroxide.~ When heated gently chromic hydroxide loses a part of its oxygen and hydrogen, forming the substance CrO.OH, which, like the corresponding aluminium compound, has more pronounced acid properties than the hydroxide. It forms a series of salts very similar to the spinels; chromite is the ferrous salt of this acid, having the formula Fe(CrO_{2})_{2}. When heated to a higher temperature chromic hydroxide is completely dehydrated, forming the trioxide Cr_{2}O_{3}. This resembles the corresponding oxides of aluminium and iron in many respects. It is a bright green powder, and when ignited strongly becomes almost insoluble in acids, as is also the case with aluminium oxide. ~Chromic sulphate~ (Cr_{2}(SO_{4})_{3}). This compound is a violet-colored solid which dissolves in water, forming a solution of the same color. This solution, however, turns green on heating, owing to the formation of basic salts. Chromic sulphate, like ferric and aluminium sulphates, unites with the sulphates of the alkali metals to form alums, of which the best known are potassium chrome alum (KCr(SO_{4})_{2}.12H_{2}O) and ammonium chrome alum (NH_{4}Cr(SO_{4})_{2}.12H_{2}O). These form beautiful dark purple crystals and have some practical uses in the tanning industry and in photography. A number of the salts of chromium are also used in the dyeing industry, for they hydrolyze like aluminium salts and the hydroxide forms a good mordant. ~Hydrolysis of chromium salts.~ When ammonium sulphide is added to a solution of a chromium salt, such as the sulphate, chromium hydroxide precipitates instead of the sulphide. This is due to the fact that chromic sulphide, like aluminium sulphide, hydrolyzes in the presence of water, forming chromic hydroxide and hydrosulphuric acid. Similarly, a soluble carbonate precipitates a basic carbonate of chromium. ~Compounds containing chromium as an acid-forming element.~ Like manganese, chromium forms two unstable acids, namely, chromic acid and dichromic acid. Their salts, the chromates and dichromates, are important compounds. ~Chromates.~ When a chromium compound is fused with an alkali and an oxidizing agent a chromate is produced. When potassium hydroxide is used as the alkali the equation is 2Cr(OH)_{3} + 4KOH + 3O = 2K_{2}CrO_{4} + 5H_{2}O. This reaction recalls the formation of a manganate und
PREV.   NEXT  
|<   269   270   271   272   273   274   275   276   277   278   279   280   281   282   283   284   285   286   287   288   289   290   291   292   293  
294   295   296   297   298   299   300   301   302   303   304   305   306   307   308   309   310   311   312   313   314   >>  



Top keywords:

chromium

 

hydroxide

 
aluminium
 

forming

 

chromic

 
sulphide
 
sulphate
 
alkali
 

solution

 

compound


Chromic
 

formation

 

carbonate

 
sulphates
 
ammonium
 
chrome
 
potassium
 

heated

 

industry

 
precipitates

number

 

dichromic

 

chromates

 

equation

 

hydrolyze

 
photography
 

dyeing

 

manganate

 

dichromates

 

Chromates


chromate

 

crystals

 
practical
 

compounds

 

tanning

 

produced

 

important

 
recalls
 

mordant

 

presence


hydrosulphuric

 

hydrolyzes

 

Similarly

 

purple

 

Compounds

 
soluble
 
element
 

reaction

 

oxidizing

 

Hydrolysis