FREE BOOKS

Author's List




PREV.   NEXT  
|<   146   147   148   149   150   151   152   153   154   155   156   157   158   159   160   161   162   163   164   165   166   167   168   169   170  
171   172   173   174   175   176   177   178   179   180   181   182   183   184   185   186   187   188   189   190   191   192   193   194   195   >>   >|  
nion of oxygen with sulphur by a lesser degree of oxygenation than the sulphuric acid. It is procurable either by burning sulphur slowly, or by distilling sulphuric acid from silver, antimony, lead, mercury, or charcoal; by which operation a part of the oxygen quits the acid, and unites to these oxydable bases, and the acid passes over in the sulphurous state of oxygenation. This acid, in the common pressure and temperature of the air, can only exist in form of gas; but it appears, from the experiments of Mr Clouet, that, in a very low temperature, it condenses, and becomes fluid. Water absorbs a great deal more of this gas than of carbonic acid gas, but much less than it does of muriatic acid gas. That the metals cannot be dissolved in acids without being previously oxydated, or by procuring oxygen, for that purpose, from the acids during solution, is a general and well established fact, which I have perhaps repeated too often. Hence, as sulphurous acid is already deprived of great part of the oxygen necessary for forming the sulphuric acid, it is more disposed to recover oxygen, than to furnish it to the greatest part of the metals; and, for this reason, it cannot dissolve them, unless previously oxydated by other means. From the same principle it is that the metallic oxyds dissolve without effervescence, and with great facility, in sulphurous acid. This acid, like the muriatic, has even the property of dissolving metallic oxyds surcharged with oxygen, and consequently insoluble in sulphuric acid, and in this way forms true sulphats. Hence we might be led to conclude that there are no metallic sulphites, were it not that the phenomena which accompany the solution of iron, mercury, and some other metals, convince us that these metallic substances are susceptible of two degrees of oxydation, during their solution in acids. Hence the neutral salt in which the metal is least oxydated must be named _sulphite_, and that in which it is fully oxydated must be called _sulphat_. It is yet unknown whether this distinction is applicable to any of the metallic sulphats, except those of iron and mercury. TABLE _of the Combinations of Phosphorous and Phosphoric Acids, with the Salifiable Bases, in the Order of Affinity._ _Names of the_ _Names of the Neutral Salts formed by_ _Bases._ _Phosphorous Acid,_ _Phosphoric Acid._ Phosphites of(B) Phosphats of(C) Lime lime
PREV.   NEXT  
|<   146   147   148   149   150   151   152   153   154   155   156   157   158   159   160   161   162   163   164   165   166   167   168   169   170  
171   172   173   174   175   176   177   178   179   180   181   182   183   184   185   186   187   188   189   190   191   192   193   194   195   >>   >|  



Top keywords:

oxygen

 

metallic

 
oxydated
 
sulphuric
 

mercury

 
metals
 

solution

 
sulphurous
 

temperature

 

sulphats


muriatic
 

sulphur

 

oxygenation

 

previously

 

Phosphoric

 

Phosphorous

 

dissolve

 

phenomena

 

convince

 

accompany


property
 

dissolving

 
surcharged
 

effervescence

 

facility

 
insoluble
 

sulphites

 

conclude

 

Combinations

 

distinction


applicable

 

Salifiable

 

Phosphats

 

Phosphites

 

formed

 
Affinity
 

Neutral

 

unknown

 

neutral

 

oxydation


degrees

 

substances

 

susceptible

 

sulphat

 

called

 
sulphite
 
common
 

pressure

 
appears
 

experiments