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sorbent power, but that artificial compounds can be formed which act upon solutions of ammonia and potash in a manner very similar to the soil; but there is not the slightest evidence that these compounds exist in the soil, and in the year 1853[I] I pointed out the probability that clay is not the only agent at work, but that the organic matters take part in the process. So powerful indeed is the affinity of these substances for ammonia, that chemists are at one as to the difficulty of obtaining humic and other similar acids pure, owing to the obstinacy with which they retain it; and there cannot be a doubt that in many soils these substances are in this point of view of much importance. This is particularly the case in peat soils, which, though naturally barren, may be made to produce good crops by the application of sand or gravel; and as neither of these can cause any absorption of the valuable matters, we must attribute this effect to the organic matter. Referring to an earlier series of experiments made in 1850, I showed that, if a quantity of dry peat be taken and ammonia poured on it, its smell disappears; and this may be continued until upwards of 1.5 per cent of dry ammonia has been absorbed, and this quantity is _retained_ by the peat. In this case pure ammonia was used, but Way's experiments having shown that this alkali is not absorbed from its salts by organic matters, I expressed the opinion that humate of lime (which certainly exists in most soils) ought on chemical grounds to decompose the salts of ammonia and cause the retention of their base. The recent researches of Brustlein have shown that lime does cause the organic matters to absorb ammonia from its salts. He confirms the fact that pure ammonia is absorbed by peat, and shows that decayed wood has the same effect, although both are without action on solutions of its salts. A stiff clay, on the other hand, containing organic matters and much carbonate of lime, readily absorbed ammonia, both when pure and combined; but after extracting the lime by means of a dilute acid, it lost the power of taking it from its salts, although it retained the free alkali as completely as before. On the addition of a small quantity of lime, it again acquired the power of withdrawing ammonia from its compounds. These experiments may be explained, either on the supposition of the presence of humate of lime, or by supposing that the carbonate of lime first decomposed the
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