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h it exists, so as to have some idea of the ease or difficulty with which they may be absorbed. For this purpose it is necessary to determine, _1st_, The substances soluble in water; _2d_, Those insoluble in water, but soluble in acids; _3d_, Those insoluble both in water and acids; and if to these the organic constituents be added, there are four separate heads under which the components of a soil ought to be classified. This classification is accordingly adopted in the most careful and minute analyses; but the difficulty and labour attending them has hitherto precluded the possibility of making them except in a few instances; and, generally speaking, chemists have been contented with treating the soil with an acid, and determining in the solution all that is dissolved. Such analyses are often useful for practical purposes, as for example, when they show the absence of lime, or any other individual substance, by the addition of which we may rectify the deficiency of the soil; but they are of comparatively little scientific value, and throw but little light on the true constitution of the soil, and the sources of its fertility. Nor is it likely that much satisfactory information will be obtained until the number of minute analyses is so far extended as to establish the fundamental principles on which the various properties of the soil depends. The separation of the constituents of a soil into the four great groups already mentioned, is effected in the following manner:--A given quantity of the soil is boiled with three or four successive quantities of water, which dissolves out all the soluble matters. These generally amount to about one-half per cent of the whole soil, and consist of nearly equal proportions of organic and inorganic substances. In very light and sandy soils, it occasionally happens that not more than one or two-tenths per cent dissolve in water, and in peaty soils, on the other hand, the proportion is sometimes considerably increased, principally owing to the abundance of soluble organic matters. When the residue of this operation is treated with dilute hydrochloric acid, the matters soluble in acids are obtained in the fluid. The proportion of these substances is liable to very great variations, and in some soils of excellent quality, and well adapted to the growth of wheat, it does not exceed 3 per cent; while in calcareous soils, such as those of the chalk formation, it may reach as much as 50 or
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