FREE BOOKS

Author's List




PREV.   NEXT  
|<   93   94   95   96   97   98   99   100   101   102   103   104   105   106   107   108   109   110   111   112   113   114   115   116   117  
118   119   120   121   122   123   124   125   126   127   128   129   130   131   132   133   134   135   136   137   138   139   140   141   142   >>   >|  
poles, or rather points, have no mutual decomposing dependence, may be shown by substituting a wire, or the finger, for one of them, a change which does not at all interfere with the other, though it stops all action at the changed pole. This fact may be observed by turning the machine for some time; for though bubbles will rise from the point left unaltered, in quantity sufficient to cover entirely the wire used for the other communication, if they could be applied to it, yet not a single bubble will appear on that wire. [A] Nicholson's Journal, 4to. vol. I. pp. 311, 299. 349. 329. When electro-chemical decomposition takes place, there is great reason to believe that the _quantity_ of matter decomposed is not proportionate to the intensity, but to the quantity of electricity passed (320.). Of this I shall be able to offer some proofs in a future part of this paper (375. 377.). But in the experiment under consideration, this is not the case. If, with a constant pair of points, the electricity be passed from the machine in sparks, a certain proportion of gas is evolved; but if the sparks be rendered shorter, less gas is evolved; and if no sparks be passed, there is scarcely a sensible portion of gases set free. On substituting solution of sulphate of soda for water, scarcely a sensible quantity of gas could be procured even with powerful sparks, and nearly none with the mere current; yet the quantity of electricity in a given time was the same in all these cases. 330. I do not intend to deny that with such an apparatus common electricity can decompose water in a manner analogous to that of the voltaic pile; I believe at present that it can. But when what I consider the true effect only was obtained, the quantity of gas given off was so small that I could not ascertain whether it was, as it ought to be, oxygen at one wire and hydrogen at the other. Of the two streams one seemed more copious than the other, and on turning the apparatus round, still the same side in relation to the machine; gave the largest stream. On substituting solution of sulphate of soda for pure water (329.), these minute streams were still observed. But the quantities were so small, that on working the machine for half an hour I could not obtain at either pole a bubble of gas larger than a small grain of sand. If the conclusion which I have drawn (377.) relating to the amount of chemical action be correct, this ought to be the case. 331. I h
PREV.   NEXT  
|<   93   94   95   96   97   98   99   100   101   102   103   104   105   106   107   108   109   110   111   112   113   114   115   116   117  
118   119   120   121   122   123   124   125   126   127   128   129   130   131   132   133   134   135   136   137   138   139   140   141   142   >>   >|  



Top keywords:

quantity

 

sparks

 

machine

 

electricity

 
passed
 

substituting

 

chemical

 
streams
 

bubble

 
apparatus

points

 

scarcely

 
action
 

sulphate

 

solution

 
evolved
 

observed

 
turning
 

intend

 

current


voltaic

 

analogous

 

manner

 
common
 

decompose

 

powerful

 

oxygen

 

minute

 

quantities

 

working


stream

 

largest

 

obtain

 

correct

 

amount

 

relating

 
conclusion
 
larger
 
relation
 

effect


obtained
 

present

 

ascertain

 

copious

 

hydrogen

 

proofs

 

communication

 

applied

 

unaltered

 

sufficient