There are many points of _electrolytic discharge_ which ultimately
will require to be very closely considered, though I can but slightly touch
upon them. It is not that, as far as I have investigated them, they present
any contradiction to the view taken (for I have carefully, though
unsuccessfully, sought for such cases), but simply want of time as yet to
pursue the inquiry, which prevents me from entering upon them here.
1354. One point is, that different electrolytes or dielectrics require
different initial intensities for their decomposition (912.). This may
depend upon the degree of polarization which the particles require before
electrolytic discharge commences. It is in direct relation to the chemical
affinity of the substances concerned; and will probably be found to have a
relation or analogy to the specific inductive capacity of different bodies
(1252. 1296.). It thus promises to assist in causing the great truths of
those extensive sciences, which are occupied in considering the forces of
the particles of matter, to fall into much closer order and arrangement
than they have heretofore presented.
1355. Another point is the facilitation of electrolytic conducting power or
discharge by the addition of substances to the dielectric employed. This
effect is strikingly shown where water is the body whose qualities are
improved, but, as yet, no general law governing all the phenomena has been
detected. Thus some acids, as the sulphuric, phosphoric, oxalic, and
nitric, increase the power of water enormously; whilst others, as the
tartaric and citric acids, give but little power; and others, again, as the
acetic and boracic acids, do not produce a change sensible to the
voltameter (739.). Ammonia produces no effect, but its carbonate does. The
caustic alkalies and their carbonates produce a fair effect. Sulphate of
soda, nitre (753.), and many soluble salts produce much effect. Percyanide
of mercury and corrosive sublimate produce no effect; nor does iodine, gum,
or sugar, the test being a voltameter. In many cases the added substance is
acted on either directly or indirectly, and then the phenomena are more
complicated; such substances are muriatic acid (758.), the soluble
protochlorides (766.), and iodides (769.), nitric acid (752.), &c. In other
cases the substance added is not, when alone, subject to or a conductor of
the powers of the voltaic battery, and yet both gives and receives power
when associated with wa
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