order to solve the question; various compounds of nearly all the
simple bodies at present known were thus passed in review, and it was
established that radioactivity was particularly perceptible in the
compounds of uranium and thorium, and that it was an atomic property
linked to the matter endowed with it, and following it in all its
combinations. In the course of her researches Madame Curie observed
that certain pitchblendes (oxide of uranium ore, containing also
barium, bismuth, etc.) were four times more active (activity being
measured by the phenomenon of the ionization of the air) than metallic
uranium. Now, no compound containing any other active metal than
uranium or thorium ought to show itself more active than those metals
themselves, since the property belongs to their atoms. It seemed,
therefore, probable that there existed in pitchblendes some substance
yet unknown, in small quantities and more radioactive than uranium.
M. and Madame Curie then commenced those celebrated experiments which
brought them to the discovery of radium. Their method of research has
been justly compared in originality and importance to the process of
spectrum analysis. To isolate a radioactive substance, the first thing
is to measure the activity of a certain compound suspected of
containing this substance, and this compound is chemically separated.
We then again take in hand all the products obtained, and by measuring
their activity anew, it is ascertained whether the substance sought
for has remained in one of these products, or is divided among them,
and if so, in what proportion. The spectroscopic reaction which we may
use in the course of this separation is a thousand times less
sensitive than observation of the activity by means of the
electrometer.
Though the principle on which the operation of the concentration of
the radium rests is admirable in its simplicity, its application is
nevertheless very laborious. Tons of uranium residues have to be
treated in order to obtain a few decigrammes of pure salts of radium.
Radium is characterised by a special spectrum, and its atomic weight,
as determined by Madame Curie, is 225; it is consequently the higher
homologue of barium in one of the groups of Mendeleef. Salts of radium
have in general the same chemical properties as the corresponding
salts of barium, but are distinguished from them by the differences of
solubility which allow of their separation, and by their enormous
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