FREE BOOKS

Author's List




PREV.   NEXT  
|<   162   163   164   165   166   167   168   169   170   171   172   173   174   175   176   177   178   179   180   181   182   183   184   185   186  
187   188   189   190   191   192   193   194   195   196   197   198   199   200   201   202   203   204   205   206   207   208   209   210   211   >>   >|  
vided nickel, serving as a catalyst, the two unite and we have alcohol, according to this reaction: C_{2}H_{4}O + H_{2} --> C_{2}H_{6}O acetaldehyde _added to_ hydrogen _forms_ alcohol Alcohol we are all familiar with--some of us too familiar, but the prohibition laws will correct that. The point to be noted is that the alcohol we have made from such unpromising materials as limestone and coal is exactly the same alcohol as is obtained by the fermentation of fruits and grains by the yeast plant as in wine and beer. It is not a substitute or imitation. It is not the wood spirits (methyl alcohol, CH_{4}O), produced by the destructive distillation of wood, equally serviceable as a solvent or fuel, but undrinkable and poisonous. Now, as we all know, cider and wine when exposed to the air gradually turn into vinegar, that is, by the growth of bacteria the alcohol is oxidized to acetic acid. We can, if we like, dispense with the bacteria and speed up the process by employing a catalyst. Acetaldehyde, which is halfway between alcohol and acid, may also be easily oxidized to acetic acid. The relationship is readily seen by this: C{2}H_{6}O --> CC_{2}H_{4}O --> C_{2}H_{4}O_{3} alcohol acetaldehyde acetic acid Acetic acid, familiar to us in a diluted and flavored form as vinegar, is when concentrated of great value in industry, especially as a solvent. I have already referred to its use in combination with cellulose as a "dope" for varnishing airplane canvas or making non-inflammable film for motion pictures. Its combination with lime, calcium acetate, when heated gives acetone, which, as may be seen from its formula (C_{3}H_{6}O) is closely related to the other compounds we have been considering, but it is neither an alcohol nor an acid. It is extensively employed as a solvent. Acetone is not only useful for dissolving solids but it will under pressure dissolve many times its volume of gaseous acetylene. This is a convenient way of transporting and handling acetylene for lighting or welding. If instead of simply mixing the acetone and acetylene in a solution we combine them chemically we can get isoprene, which is the mother substance of ordinary India rubber. From acetone also is made the "war rubber" of the Germans (methyl rubber), which I have mentioned in a previous chapter. The Germans had been getting about half their supply of acetone from American acetate of lime and this was of c
PREV.   NEXT  
|<   162   163   164   165   166   167   168   169   170   171   172   173   174   175   176   177   178   179   180   181   182   183   184   185   186  
187   188   189   190   191   192   193   194   195   196   197   198   199   200   201   202   203   204   205   206   207   208   209   210   211   >>   >|  



Top keywords:

alcohol

 

acetone

 

rubber

 

solvent

 
acetic
 
acetylene
 

familiar

 

methyl

 

acetate

 

catalyst


acetaldehyde

 
vinegar
 

Germans

 

combination

 
bacteria
 

oxidized

 
closely
 
supply
 
compounds
 

related


heated

 

canvas

 
making
 

airplane

 

varnishing

 
inflammable
 

extensively

 

American

 
calcium
 
motion

pictures
 

formula

 
solids
 
mixing
 

solution

 

combine

 

simply

 

welding

 
chemically
 

mentioned


ordinary

 
substance
 

previous

 

isoprene

 

mother

 

chapter

 

lighting

 

pressure

 

dissolve

 

dissolving