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-activity. The underlying principle was unknown and even the statement of what was sometimes erroneously called the Periodic Law was manifestly incorrect and its terms were ignored. Basis of the Periodic System The ordinary statement of the fundamental principle of the Periodic System has been that the properties of the elements were periodic functions of the atomic weights, and that when the elements were arranged in the order of their atomic weights they fell into a natural series, taking their places in the proper related groups. In accepting this, the interpretation of function was both unmathematical and vague, and the order of the atomic weights was not strictly adhered to but unhesitatingly abandoned to force the group relationship. Wherever consideration of the atomic weight would have placed an element out of the grouping with other elements to which it was clearly related in physical and chemical properties, the guidance of these properties was accepted and that of the atomic weights disregarded. Such shiftings are noted in the cases of tellurium and iodine; cobalt and nickel; argon and potassium. It was most helpful that, following the order of atomic weights, the majority of the elements fell naturally into their places. Otherwise the generalization known as the Periodic System might have remained for a long time undiscovered and the progress of chemistry would have been greatly retarded. Influence of Positive Nucleus It is evident that the order of the elements is determined by something else than their atomic weights. From the known facts of radio-activity it would seem that this determining factor is the positive nucleus. And this nucleus also determines the mass or weight of the atom. Taking the elements in their order in the Periodic Series and numbering the positions held by them in this series as 1, 2, 3, etc., we get the position number or what is called the atomic number. This designates the order or position of the element in the series. We must learn that this number marks a position rather than a single element, a statement which will be explained later. Determination of the Atomic Number Since the atomic weight is unreliable as a means of settling the position of an element in the series and so fixing its atomic number, how is this number to be determined? Of course, one answer to this question is that we may rely upon a consideration of the general properties, as has been
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