FREE BOOKS

Author's List




PREV.   NEXT  
|<   39   40   41   42   43   44   45   46   47   48   49   50   51   52   53   54   55   56   57   58   59   60   61   62   63  
64   65   66   67   68   69   70   71   72   73   74   75   76   77   78   79   80   81   82   83   84   85   86   87   88   >>   >|  
eated "contact" substance, usually some form of finely-divided platinum. _Nitric Acid._--This acid is usually prepared by distilling a mixture of sodium nitrate and vitriol in cast-iron retorts or pots, the nitric acid being collected in stoneware vessels connected one with another, or, as is more generally the case at the present time, in condensing apparatus consisting of stoneware pipes or coils cooled by water. The effluent gases are passed through a scrubber in order to free them from the last traces of acid before discharging them into the atmosphere. _Hydrochloric Acid._--The greater part of the hydrochloric acid manufactured in Great Britain is obtained as an intermediate product in the Leblanc alkali process, which will presently be described, being produced by heating common salt with vitriol. A large quantity is, however, also produced by the so-called direct process of Hargreaves & Robinson, which is, in principle, the same method as that employed in the Leblanc process, except that the intermediate product, vitriol, is not separated. It consists essentially in passing the hot gases from pyrites kilns, as used in the manufacture of vitriol, through large cast-iron vessels containing common salt heated to a high temperature. Various physical conditions must be complied with in order to make the process a success. For example, the salt is used in the form of moulded hard porous cakes made from a damp mixture of common salt and rock salt. The cast-iron vessels must be heated uniformly, and the hot pyrites kiln gases must be passed downwards through the salt in order to ensure uniform distribution. The hydrochloric acid is condensed in stoneware pipes connected with towers packed with coke or stoneware. _Alkali: Leblanc Process._--The manufacture of vitriol, as I have described it to you, is the first step in the Leblanc process. The next stage consists in the manufacture of sodium sulphate (salt-cake) and hydrochloric acid from the sulphuric acid and common salt; this is called the salt-cake process. The production of salt-cake or crude sodium sulphate is carried out in two stages. A large covered iron pan, called the decomposing pan or salt-cake pot, is mounted in one part of the salt-cake furnace, and alongside it is the hearth or bed on which the second stage of the process, the drying or roasting, is effected. The mixture of common salt and vitriol is charged into the salt-cake pot, which is heated by
PREV.   NEXT  
|<   39   40   41   42   43   44   45   46   47   48   49   50   51   52   53   54   55   56   57   58   59   60   61   62   63  
64   65   66   67   68   69   70   71   72   73   74   75   76   77   78   79   80   81   82   83   84   85   86   87   88   >>   >|  



Top keywords:

process

 

vitriol

 
common
 

Leblanc

 

stoneware

 

hydrochloric

 

vessels

 

manufacture

 

called

 

sodium


mixture

 
heated
 
pyrites
 

produced

 
consists
 
intermediate
 

product

 

passed

 

connected

 

sulphate


moulded

 

furnace

 

mounted

 

alongside

 

hearth

 

porous

 

drying

 

roasting

 

charged

 
effected

temperature

 

Various

 
success
 

complied

 

physical

 
conditions
 

carried

 
Process
 

Alkali

 
production

sulphuric

 

packed

 

stages

 
uniformly
 

covered

 

decomposing

 
condensed
 

towers

 

distribution

 
uniform