ndensation of the gases
worthy of your attention. Most aeriform bodies, when subjected to
compression, are made to occupy a space which diminishes in the
exact ratio of the increase of the compressing force. Very
generally, under a force double or triple of the ordinary
atmospheric pressure, they become one half or one third their former
volume. This was a long time considered to be a law, and known as
the law of Marriotte; but a more accurate study of the subject has
demonstrated that this law is by no means of general application.
The volume of certain gases does not decrease in the ratio of the
increase of the force used to compress them, but in some, a
diminution of their bulk takes place in a far greater degree as the
pressure increases.
Again, if ammoniacal gas is reduced by a compressing force to
one-sixth of its volume, or carbonic acid is reduced to one
thirty-sixth, a portion of them loses entirely the form of a gas,
and becomes a liquid, which, when the pressure is withdrawn, assumes
again in an instant its gaseous state--another deviation from the
law of Marriotte.
Our process for reducing gases into fluids is of admirable
simplicity. A simple bent tube, or a reduction of temperature by
artificial means, have superseded the powerful compressing machines
of the early experimenters.
The cyanuret of mercury, when heated in an open glass tube, is
resolved into cyanogen gas and metallic mercury; if this substance
is heated in a tube hermetically sealed, the decomposition occurs as
before, but the gas, unable to escape, and shut up in a space
several hundred times smaller than it would occupy as gas under the
ordinary atmospheric pressure, becomes a fluid in that part of the
tube which is kept cool.
When sulphuric acid is poured upon limestone in an open vessel,
carbonic acid escapes with effervescence as a gas, but if the
decomposition is effected in a strong, close, and suitable vessel of
iron, we obtain the carbonic acid in the state of liquid. In this
manner it may be obtained in considerable quantities, even many
pounds weight. Carbonic acid is separated from other bodies with
which it is combined as a fluid under a pressure of thirty-six
atmospheres.
The curious properties of fluid carbonic acid are now generally
known. When a small quantity is permitted to escape into the
atmosphere, it assumes its gaseous state with extraordinary
rapidity, and deprives the remaining fluid of caloric so rapidl
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