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h to exhibit such a satisfactory picture of the building as had been hoped for. The outline of the roof and of the chimneys, &c. against the sky was marked enough; but the details of the architecture were feeble, and the parts in shade were left either blank or nearly so. The sensitiveness of the paper to light, considerable as it seemed in some respects, was therefore, as yet, evidently insufficient for the purpose of obtaining pictures with the Camera Obscura; and the course of experiments had to be again renewed in hopes of attaining to some more important result. The next interval of sufficient leisure which I found for the prosecution of this inquiry, was during a residence at Geneva in the autumn of 1834. The experiments of the previous spring were then repeated and varied in many ways; and having been struck with a remark of Sir H. Davy's which I had casually met with--that the _iodide_ of silver was more sensitive to light than the _chloride,_ I resolved to make trial of the iodide. Great was my surprise on making the experiment to find just the contrary of the fact alleged, and to see that the iodide was not only less sensitive than the chloride, but that it was not sensitive at all to light; indeed that it was absolutely insensible to the strongest sunshine: retaining its original tint (a pale straw colour) for any length of time unaltered in the sun. This fact showed me how little dependance was to be placed on the statements of chemical writers in regard to this particular subject, and how necessary it was to trust to nothing but actual experiment: for although there could be no doubt that Davy had observed what he described under certain circumstances--yet it was clear also, that what he had observed was some exception to the rule, and not the rule itself. In fact, further inquiry showed me that Davy must have observed a sort of subiodide in which the iodine was deficient as compared with the silver: for, as in the case of the chloride and subchloride the former is much less sensitive, so between the iodide and subiodide there is a similar contrast, but it is a much more marked and complete one. However, the fact now discovered, proved of immediate utility; for, the iodide of silver being found to be insensible to light, and the chloride being easily converted into the iodide by immersion in iodide of potassium, it followed that a picture made with the chloride could be _fixed_ by dipping it into a ba
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