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the force of the heat, and the black lead, which still retained the form of a loose and subtile powder, yielded little or nothing to water. We learn then from the above experiment the reason why the alkali newly obtained from the ashes of vegetables is generally of the more acrid kinds of that salt. It never appears until the subject be converted into ashes, and is supposed to be formed by the fire, and to be the result of a particular combination of some of the principles of the vegetable; one of which principles is air, which is contained in large quantity in all vegetable matters whatever. But as soon as the smallest part of a vegetable is converted into ashes, and an alkali is thus formed, this salt necessarily suffers a calcination, during which it is kept in a spongy form by the ashes, and shews a very considerable degree of acrimony if immediately applied to the body of an animal but if the ashes are for any time exposed to the air, or if we separate the alkali from them by the addition of a large quantity of water and subsequent evaporation, the salt imbibes fixed air from the atmosphere, and becomes nearly saturated with it: tho' even in this condition it is generally more acrid than salt of tartar, when this is prepared with a gentle heat. Borax has sometimes been referred to the class of alkalis, on account of some resemblance it bears to those salts: but it has been demonstrated by accurate experiments, that we should rather consider it as a neutral salt; that it is composed of an alkali and of a particular saline substance called the sedative salt, which adheres to the alkali in the same manner as an acid, but can be separated by the addition of any acid whatever, the added acid joining itself to the alkali in the place of the sedative salt. As this conjunction of an acid with the alkali of borax happens without the least effervescence, our principles lay us under a necessity of allowing that alkali to be perfectly free of air, which must proceed from its being incapable of union with fixed air and with the sedative salt at the same time: whence it follows, that, were we to mix the sedative salt with an alkali saturated with air, the air would immediately be expelled, or the two salts in joining would produce an effervescence. This I found to be really the case upon making the trial, by mixing a small quantity of the sedative salt with an equal quantity of each of the three alkalis, rubbing the mixtures
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