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the dye, is nearly as good an absorber of heat as the snow around it. But to the absorption of the dark solar rays by the undyed cloth, is now added the absorption of the whole of the luminous rays, and this great additional influx of heat is far more than sufficient to turn the balance in favour of the black cloth. The sum of its actions on the dark and luminous rays, exceeds the action of the snow on the dark rays alone. Hence the cloth will sink in the snow, and this is the complete analysis of Franklin's experiments. Throughout this discourse the main stress has been laid on chemical constitution, as influencing most powerfully the phenomena of radiation and absorption. With regard to gases and vapours, and to the liquids from which these vapours are derived, it has been proved by the most varied and conclusive experiments that the acts of radiation and absorption are molecular--that they depend upon chemical, and not upon mechanical, condition. In attempting to extend this principle to solids I was met by a multitude of facts, obtained by celebrated experimenters, which seemed flatly to forbid such an extension. Mellon, for example, had found the same radiant and absorbent power for chalk and lamp-black. MM. Masson and Courtepee had performed a most elaborate series of experiments on chemical precipitates of various kinds, and found that they one and all manifested the same power of radiation. They concluded from their researches, that when bodies are reduced to an extremely fine state of division, the influence of this state is so powerful as entirely to mask and override whatever influence may be due to chemical constitution. But it appears to me that through the whole of these researches an oversight has run, the mere mention of which will show what caution is essential in the operations of experimental philosophy; while an experiments or two will make clear wherein the oversight consists. Filling a brightly polished metal cube with boiling water, I determine the quantity of heat emitted by two of the bright surfaces. As a radiator of heat one of them far transcends the other. Both surfaces appear to be metallic; what, then, is the cause of the observed difference in their radiative power? Simply this: one of the surfaces is coated with transparent gum, through which, of course, is seen the metallic lustre behind; and this varnish, though so perfectly transparent to luminous rays, is as opaque as
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