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vestigation of the mode in which certain metals are reduced from their solutions by metallic sulphides, or, in common language, the influence which the presence of such substances as mundic and galena may exercise in effecting the deposit of pure metals, such as gold, in mineral lodes. The close relation which the richness of gold veins bears to the prevalence of pyrites has been long familiar both to scientific observers and to practical miners. The gold is an after deposit to the pyrites, and, as Mr. Skey was the first to explain, due to its direct reducing influences. By a series of experiments Mr. Skey proved that the reduction of the metal was due to the direct action of the sulphide, and showed that each grain of iron pyrites, when thoroughly oxidised, will reduce 12 1/4 grains of gold from its solution as chloride. He also included salts of platina and silver in this general law, and demonstrated that solutions of any of these metals traversing a vein rock containing certain sulphides would be decomposed, and the pure metal deposited. We are thus enabled to comprehend the constant association of gold, or native alloys of gold and silver, in veins which traverse rocks containing an abundance of pyrites, whether they have been formed as the result of either sub-aqueous volcanic outburst or by the metamorphism of the deeper-seated strata which compose the superficial crust of the earth. Mr. Skey also showed by very carefully conducted experiments that the metallic sulphides are not only better conductors of electricity than has hitherto been supposed, but that when paired they were capable of exhibiting strong electro-motive power. Thus, if galena and zinc blende in acid solutions be connected in the usual manner by a voltaic pair, sulphuretted hydrogen is evolved from the surface of the former, and a current generated which is sufficient to reduce gold, silver or copper from their solutions in coherent electro-plate films. The attributing of this property of generating voltaic currents, hitherto supposed to be almost peculiar to metals, to such sulphides as are commonly found in metalliferous veins, further led Mr. Skey to speculate how far the currents discovered to exist in such veins by Mr. E. F. Fox might be produced by the gradual oxidation of mixed sulphides, and that veins containing bands of different metallic sulphides, bounded by continuing walls, and saturated with mineral waters, may constitute under s
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