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r without any elevation of temperature, merely by taking off the weight of the atmosphere. In such liquids, you perceive, it is the pressure of the atmosphere alone that connects their particles, and keeps them in a liquid state. CAROLINE. I do not well understand why the particles of such fluids should be disunited and converted into vapour, without any elevation of temperature, in spite of the attraction of cohesion. MRS. B. It is because the degree of heat at which we usually observe these fluids is sufficient to overcome their attraction of cohesion. Ether is of this description; it will boil and be converted into vapour, at the common temperature of the air, if the pressure of the atmosphere be taken off. EMILY. I thought that ether would evaporate without either the pressure of the atmosphere being taken away, or heat applied; and that it was for that reason so necessary to keep it carefully corked up? MRS. B. It is true it will evaporate, but without ebullition; what I am now speaking of is the vaporization of ether, or its conversion into vapour by boiling. I am going to show you how suddenly the ether in this phial will be converted into vapour, by means of the air-pump. --Observe with what rapidity the bubbles ascend, as I take off the pressure of the atmosphere. CAROLINE. It positively boils: how singular to see a liquid boil without heat! MRS. B. Now I shall place the phial of ether in this glass, which it nearly fits, so as to leave only a small space, which I fill with water; and in this state I put it again under the receiver. (PLATE IV. Fig. 1.)* You will observe, as I exhaust the air from it, that whilst the ether boils, the water freezes. [Footnote *: Two pieces of thin glass tubes, sealed at one end, might answer this purpose better. The experiment, however, as here described, is difficult, and requires a very nice apparatus. But if, instead of phials or tubes, two watch-glasses be used, water may be frozen almost instantly in the same manner. The two glasses are placed over one another, with a few drops of water interposed between them, and the uppermost glass is filled with ether. After working the pump for a minute or two, the glasses are found to adhere strongly together, and a thin layer of ice is seen between them.] CAROLINE. It is indeed wonderful to see water freeze in contact with a boiling fluid! EMILY. I am
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