FREE BOOKS

Author's List




PREV.   NEXT  
|<   83   84   85   86   87   88   89   90   91   92   93   94   95   96   97   98   99   100   101   102   >>  
in the cold in contact with fluorine, and if the fluorine is led into the midst of the liquid a similar production of flame occurs under the surface of the liquid, as in case of nitric acid. No carbon is deposited, both the carbon and sulphur being entirely converted into gaseous fluorides. _Carbon tetrachloride_, as previously mentioned, reacts only very slowly with fluorine. The liquid may be saturated with gaseous fluorine at 15 deg., but on boiling this liquid a gaseous mixture is evolved, one constituent of which is carbon tetrafluoride, CF_{4}, a gas readily capable of absorption by alcoholic potash. The remainder consists of another fluoride of carbon, incapable of absorption by potash and chlorine. A mixture of the vapors of carbon tetrachloride and fluorine inflames spontaneously with detonation, and chlorine is liberated without deposition of carbon. _Boric anhydride_ is raised to a most vivid incandescence by fluorine, the experiment being rendered very beautiful by the abundant white fumes of the trifluoride which are liberated. _Silicon dioxide_, one of the most inert of substances at the ordinary temperature, takes fire in the cold in contact with fluorine, becoming instantly white-hot, and rapidly disappearing in the form of silicon tetrafluoride. The _chlorides_ of both _boron_ and _silicon_ are decomposed by fluorine, with formation of fluorides and liberation of chlorine, the reaction being accompanied by the production of flame. ACTION OF FLUORINE UPON METALLIC COMPOUNDS. _Chlorides_ of the metals are instantly decomposed by fluorine, generally at the ordinary temperature, and in certain cases, antimony trichloride for instance, with the appearance of flame. Chlorine is in each case liberated, and a fluoride of the metal formed. A few require heating, when a similar decomposition occurs, often accompanied by incandescence, as in case of chromium sesquichloride. _Bromides_ and _iodides_ are decomposed with even greater energy, and the liberated bromine and iodine burn in the fluorine with formation of their respective fluorides. _Cyanides_ react in a most beautiful manner with fluorine, the displaced cyanogen burning with a purple flame. Potassium ferrocyanide in particular affords a very pretty experiment, and reacts in the cold. Ordinary potassium cyanide requires slightly warming in order to start the combustion. Fused _potash_ yields potassium fluoride and ozone. Aqueous potash
PREV.   NEXT  
|<   83   84   85   86   87   88   89   90   91   92   93   94   95   96   97   98   99   100   101   102   >>  



Top keywords:

fluorine

 

carbon

 
potash
 

liquid

 

liberated

 

decomposed

 

chlorine

 

fluorides

 

gaseous

 
fluoride

absorption

 
mixture
 
tetrafluoride
 
silicon
 
formation
 

accompanied

 

potassium

 

instantly

 

temperature

 

incandescence


beautiful

 

ordinary

 

experiment

 

tetrachloride

 

reacts

 

occurs

 

production

 

similar

 
contact
 

appearance


Chlorine

 

instance

 

antimony

 

trichloride

 
formed
 
decomposition
 

heating

 
require
 
FLUORINE
 

ACTION


Aqueous
 
METALLIC
 

COMPOUNDS

 

yields

 

generally

 

metals

 

Chlorides

 

chromium

 

sesquichloride

 

ferrocyanide