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ill be less than that of a particle which has retained its positive charge for the whole of its journey, while the few particles which have a negative charge for a longer time than they have a positive will be deflected in the opposite direction to the main portion and will produce the tail (fig. 27). [Illustration: Fig. 27.] A similar explanation will apply to the positive rays discovered by Villard (_Comptes rendus_, 143, p. 674) and J. J. Thomson (_Phil. Mag._ 13, p. 359), which travel in the opposite direction to the rays we have been considering, i.e. they travel away from the cathode and in the direction of the cathode's rays; these rays are sometimes called "retrograde" rays. These as far as has been observed have always the same maximum value of e/m, i.e. 10^4, and there are a considerable number of negative ones always mixed with them. The maximum velocity of both the positive and retrograde rays is about 2 X 10^8 cm./sec. and varies very little with the potential difference between the electrodes in the tube in which they are produced (J. J. Thomson, _Phil. Mag._, Dec. 1909). The positive rays show, when the pressure is not very low, the line spectrum of the gas through which they pass. An exceedingly valuable set of observations on this point have been made by Stark and his pupils (_Physik. Zeit._ 6, p. 892; _Ann. der Phys._ 21, pp. 40, 457). Stark has shown that in many gases, notably hydrogen, the spectrum shows the Doppler effect, and he has been able to calculate in this way the velocity of the positive rays. _Anode Rays._--Gehrcke and Reichenhein (_Ann. der Phys._ 25, p. 861) have found that when the anode consists of a mixture of sodium and lithium chloride raised to a high temperature either by the discharge itself or by an independent heating circuit, very conspicuous rays come from the anode when the pressure of the gas in the discharge tube is very low, and a large coil is used to produce the discharge. The determination of e/m for these rays showed that they are positively charged atoms of sodium or lithium, moving with very considerable velocity; in some of Gehrcke's experiments the maximum velocity was as great as 1.8 X 10^7 cm./sec. though the average was about 10^7 cm./sec. These velocities are less than those of the positive rays whose maximum velocity is about 2 X 10^8 cm./sec. (J. J. T.) FOOTNOTES: [1] The values for nickel and bismuth given in the table are much h
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