FREE BOOKS

Author's List




PREV.   NEXT  
|<   134   135   136   137   138   139   140   141   142   143   144   145   146   147   148   149   150   151   152   153   154   155   156   157   158  
159   160   161   162   163   164   165   166   167   168   169   170   171   172   173   174   175   176   177   178   179   180   181   182   183   >>   >|  
, C_{13}H_{27}.COOH, in cocoanut oil and spermaceti. (6) Palmitic acid, C_{15}H_{31}.COOH, in palm oil and many fats. (7) Stearic acid, C_{17}H_{35}.COOH, in most fats and oils. Intervening members of this series, such as caprylic acid, C_{7}H_{15}.COOH, and lauric acid, C_{11}H_{23}.COOH, are also found in smaller quantities in cocoanut and palm nut oils, in butter fat, and in spermaceti; while higher members of the series, as arachidic acid, C_{19}H_{39}.COOH, and lignoceric acid, C_{23}H_{47}.COOH, are found in peanut oil; and cerotic acid, C_{25}H_{51}.COOH, and melissic acid, C_{29}H_{59}.COOH, in beeswax and carnauba wax. Unsaturated Acids: (_b_) Oleic acid series--general formula, C_{_n_}H_{2_n_-1}.COOH. (1) Crotonic acid, C_{3}H_{5}.COOH, occurs in croton oil. (2) Oleic acid, C_{17}H_{33}.COOH, occurs in many fats and oils. (3) Brassic acid, C_{21}H_{41}.COOH, occurs in rape-seed oil. (4) Ricinoleic acid, C_{17}H_{32}OH.COOH, occurs in castor oil. (_c_) Linoleic acid series--general formula, C_{_n_}H_{2_n_-3}.COOH. (1) Linoleic acid, C_{17}H_{31}.COOH, occurs in linseed and other drying oils. (_d_) Linolenic acid series--general formula, C_{_n_}H_{2_n_-5}.COOH. (1) Linolenic acid, C_{17}H_{29}.COOH, occurs in many drying oils. It will be observed that all of these acids contain a multiple of two total carbon atoms. No acid containing an uneven number of carbon atoms has been found in a natural fat. Furthermore, the acids which occur most commonly in natural fats are those which contain eighteen carbon atoms; in fact, more than 80 per cent of the glycerides which compose all animal and vegetable fats are those of the C_{18} acids. This fact, in addition to the one that the sugars and starches all contain multiples of six carbon atoms in their molecules, indicates a very great biological significance of the chain of six carbon atoms. This has been alluded to in connection with the discussion of the biological significance of molecular configuration (see page 57) and will be mentioned again in other connections. THE ALCOHOLS WHICH OCCUR IN NATURAL FATS =Glycerol=, as has been pointed out, is by far the most common alcoholic constituent of natural fats and oils. This substance, wh
PREV.   NEXT  
|<   134   135   136   137   138   139   140   141   142   143   144   145   146   147   148   149   150   151   152   153   154   155   156   157   158  
159   160   161   162   163   164   165   166   167   168   169   170   171   172   173   174   175   176   177   178   179   180   181   182   183   >>   >|  



Top keywords:

occurs

 
carbon
 

series

 

general

 

formula

 

natural

 
significance
 

biological

 

drying

 

Linoleic


Linolenic
 
spermaceti
 

members

 

cocoanut

 

compose

 

animal

 

Glycerol

 
glycerides
 
pointed
 

commonly


Furthermore
 
substance
 

constituent

 

alcoholic

 

common

 

vegetable

 
eighteen
 
mentioned
 

discussion

 

molecular


connection

 

alluded

 
connections
 

starches

 

multiples

 

sugars

 

configuration

 
addition
 

NATURAL

 

molecules


ALCOHOLS
 
linseed
 

arachidic

 
higher
 
butter
 

lignoceric

 

melissic

 
peanut
 

cerotic

 
quantities